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steriods UV/Vis and EPR spectroscopic studies on the oxidised species [MRLoNMe]+ (M= Zn, Ni steroids for women, Cu; R = Ph, PhMe, PhOMe, tBu/Ph, tBu/PhMe, tBu/PhOMe) steroids for women, supported by DFT calculations, suggest that the first oxidation process is significantly more metal based when M = Ni than for M = Cu or Zn and for the generation of [NiRLoNMe]+ is associated with the formation of formal NiIII species. The UV/vis and EPR spectroscopic results also suggest that [NiPhOMeLoNMe]+ exhibits temperature dependent NiIII phenolate NiII phenoxyl redox tautomerism. The variation of the aromatic substituents systematically decreases the redox potential in the order R = Ph > PhMe > PhOMe, consistent with the relative electron donor properties of each group.Chapter Four examines complexes that incorporate an aromatic, N donor group pendant to the ligand background. steriods

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